WANG CHANGCHENG, HU HONGLI, LI LONG, et al. Research Progress of Transition Metal Oxides in Super Capacitor. [J]. Power capacitor & reactive power compensation, 2020, 41(5): 81-87.
WANG CHANGCHENG, HU HONGLI, LI LONG, et al. Research Progress of Transition Metal Oxides in Super Capacitor. [J]. Power capacitor & reactive power compensation, 2020, 41(5): 81-87. DOI: 10.14044/j.1674-1757.pcrpc.2020.05.014.
Research Progress of Transition Metal Oxides in Super Capacitor
摘要
储能作为新能源技术中最重要的组成部分之一
在当今社会中扮演着越来越重要的角色
是当前的研究热点;加快储能技术的创新开发是解决未来新能源产业发展的关键环节
具有迫切的市场需求。超级电容器作为一种新型储能器件
具有电容量大、功率密度高、充电速度快、循环寿命长、温度范围宽、免维护、安全环保等诸多优点
近些年来发展迅速。但其能量密度较低
限制了大规模应用
需要设法进行优化提高。目前
各类过渡金属氧化物因具有较高的比电容而得到重视
被作为电极材料用于超级电容器中
通过氧化还原反应的方式储存和释放大量能量
可以较大幅度地提高能量密度。各类过渡金属氧化物如RuO2、MnO2、NiO等各有优缺点
本文分别介绍了不同过渡金属氧化物的各种制备方法
并对他们的缺点如电导率低、循环稳定性差等提出了多种解决方案。此外
还介绍了部分混合过渡金属氧化物的电化学性能以及与各类高导电性碳纳米材料复合之后的电化学性能
并对过渡金属氧化物目前的研究方向进行了总结。
Abstract
As one of the most important components of new energy technology
energy storage plays an increasingly important role in today
s society and is the current research hotspot;accelerating the innovation and development of energy storage technology is the key to solve the future development of new energy industry in accordance with market demands.As a new type of energy storage device
supercapacitor has many advantages
such as large capacity
high power density
fast charging speed
long cycle life
wide temperature range
maintenance free
safety and environmental protection
etc.However
its low energy density lim
its its large-scale application
and it needs to be optimized and improved.At present
all kinds of transition metal oxides have been paid attention to because of their high specific capacitance.They are used as electrode materials in supercapacitors.By means of oxidation-reduction reaction to store and release a large amount of energy
the energy density can be greatly improved.All kinds of transition metal oxides
such as RuO
2
MnO
2
NiO etc
have their own advantages and disadvantages.In this paper
various preparation methods of different transition metal oxides are introduced
and a variety of solutions are proposed for their disadvantages
such as low conductivity and poor cycle stability.In addition
the electrochemical properties of some mixed transition metal oxides and their composites with various high conductivity carbon nanomaterials are also introduced
and the current research directions of transition metal oxides are summarized.
关键词
储能超级电容器过渡金属氧化物碳纳米材料复合材料
Keywords
energy storagesupercapacitortransition metal oxidecarbon nanomaterialcomposite